Iron-modulated nickel cobalt phosphide embedded in carbon to boost power density of hybrid sodium–air battery

نویسندگان

چکیده

Nickel cobalt phosphide (NiCoP) is emerging as a potential electrocatalyst towards oxygen reduction reaction (ORR) and evolution (OER). However, its ORR/OER activities are sluggish. Here, we investigated the roles of iron dopants in Fe-doped NiCoP (Fe–NiCoP) order to boost kinetics. The density functional theory (DFT) calculations reveal that Fe dopant effectively modulates electron conductivity reduces binding energies intermediates rate-determining steps ORR OER. A binder-free 3D microflowers morphology Fe–NiCoP embedded amorphous carbon layer (Fe–[email protected]) catalyst on nickel foam was prepared air cathode for hybrid sodium-air battery (HSAB). HSAB displays discharge voltage 2.74 V at 0.01 mA cm?2 with excellent round trip efficiency 93.26 % 500th cycle state-of-the-art power 621 mW g?1.

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ژورنال

عنوان ژورنال: Applied Catalysis B-environmental

سال: 2021

ISSN: ['1873-3883', '0926-3373']

DOI: https://doi.org/10.1016/j.apcatb.2020.119786